KMSF® 2000 Low Dk/Df Photo-dielectric

Part of the Kayaku Advanced Materials Line

KMSF® 2000 is a negative-tone, low-temperature cure, PPE-copolymer-based photo-dielectric for high reliability heterogeneous design in advanced packaging. It provides a unique advantage offering through its improved pattern resolution, low temperature cure, and robust balance of mechanical and electrical properties.

10 µm via
10 µm Film Thickness

KMSF® 2000 provides excellent performance with a low dielectric constant (Dk = 2.5) and a low dissipation factor (Df = 0.003), making it ideal for applications that require high-frequency reliability and signal integrity. It is engineered for an optimal cured film thickness of 5 to 10 μm, providing versatility and consistency in high-performance electronic packaging solutions.

15 µm via
10 µm Film Thickness

Plating
Deep Etch

Cured Film Properties

Process
Available Viscosities ~800 cSt
~1600 cSt
Mechanical Properties
Young's Modulus 1.6 GPa
Tensile Strength 60 MPa
CTE α1 (<Tg) 60 ppm/°C
Elongation 65%
Residual Stress 14 MPa
Electrical Properties
Volume Resistivity 6.7 x 1016 Ohm cm
Breakdown Voltage 270 V/µm
Dielectric Constant (10-50 GHz) 2.5
Dielectric Factor (10-50 GHz) 0.003
Thermal Properties
Tg (DMA) 215°C
5% Weight Loss Temperature in N₂ 390°C
Water Absorption
Moisture Absorption (23°C/85%RH, 24 hours) 0.03%

Key Features

  • Negative tone, photoimageable dielectric
  • 5 to 10 µm film thickness after cure
  • Solvent-developable in PGMEA
  • I-Line/broadband sensitivity, 1:1 aspect ratio imaging
  • Low temperature cure ≤ 200°C
  • Low Dk/Df electrical properties
  • Low moisture uptake
  • Good thermal and chemical stability

Material Uses

RDL dielectric

Passivation and protective layer

Wafer level packaging

Process Parameters

Coat

KMSF® 2000 resist is available in two standard viscosities to cover a final cured film thickness of 5-10 µm. The post soft bake, as coated film thickness vs. spin speed, is displayed in Figure 2.

Please note the exact thickness obtained may be slightly offset from Figure 2. due to equipment type, setting differences and room conditions.

Recommended Program

1.Dispense 1 ml of resist for each inch (25 mm) of substrate diameter
2.Spin at 500 rpm for 5–10 seconds with acceleration of 500 rpm/second
3.Spin at 1000-3500 rpm for 30 seconds with acceleration of 500 rpm/second

Soft Bake

A 95°C soft bake for 2 to 4 minutes depending on the film thickness on a level hot plate with good thermal control and uniformity is recommended.

Exposure

KMSF® 2000 is compatible with i-Line and broadband exposure tools. Bulk film thickness loss associated with exposure and development is typically observed. A minimal broadband exposure dose of 250 mJ/cm2 (high pressure Hg vapor lamp) measured at 365 nm is recommended.

Development

KMSF® 2000 resist is optimized for development in PGMEA using immersion, spray, puddle, or spray/ puddle methods. For a 5 µm and 10 µm cured film thickness, 6 x 60 seconds puddle steps are recommended.

Bulk film thickness losses associated with the exposure and development are typically observed postdevelopment. Film loss and shrinkage data is depicted in Figure 4.